SCHOLLE CORP -- BATTERY FLUID, ACID -- 6810-00-236-0702
===================== Product Identification ===================== Product ID:BATTERY FLUID, ACID MSDS Date:07/01/1998 FSC:6810 NIIN:00-236-0702 Status Code:A === Responsible Party === Company Name:SCHOLLE CORP Address:200 W NORTH AVE City:NORTHLAKE State:IL ZIP:60164 Country:US Info Phone Num:708-562-7290 Emergency Phone Num:708-562-7290, CHEMTREC 800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO439 === Contractor Identification === Company Name:SCHOLLE CORP Address:200 W NORTH AVE Box:City:MELROSE PARK State:IL ZIP:60164-2402 Country:US Phone:708-562-7290 Contract Num:SP0450-00-M-D272 CAGE:97807 Company Name:SCHOLLE CORP Address:200 W NORTH AVE Box:City:NORTHLAKE State:IL ZIP:60164 Country:US Phone:708-562-7290 CAGE:TO439 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 34-36% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 64-66% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:THIRD DEGREE BURNS. SEVERE RESPIRATORY, SKIN, AND EYE IRRITANT. BRONCHITIS, LARYNGEAL AND PULMONARY EDEMA MAY RESULT. Explanation of Carcinogenicity:IARC LISTS A POSSIBLE LINK BETWEEN SULFURIC ACID EXPOSURE & LARYNGEAL CANCER W/INSUFFICIENT DATA FOR CONFIRMATION. Effects of Overexposure:PRICKLING OR BURNING SENSATION OF SKIN AND MUCOUS MEMBRANES. COUGHING, SNEEZING, TIGHTNESS OF CHEST, DIFFICULTY IN BREATHING. Medical Cond Aggravated by Exposure:ANY PRE-EXISTING RESPIRATORY DISEASE, FOR EXAMPLE EMPHYSEMA. ======================= First Aid Measures ======================= First Aid:SEE SUPP DATA. GET IMMEDIATE MEDICAL ATTENTION!! EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. AID OR RESTO RE BREATHING AS NEEDED. INGESTED:DO NOTINDUCE VOMITING. GIVE LARGE QUANTITIES OF MILK, MILK OF MAGNESIA, TABLE OIL, EGGS OR WATER TO DRINK. GET IMMEDIATE MEDICAL ATTENTION. RINSE MOUTH OFTEN. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE FOR SMALL FIRES. WATER FOG, LARGE FIRES. Fire Fighting Procedures:DO NOT DIRECT WATER INTO ACID TANKS. COOL OUTSIDE OF TANK W/WATER. WEAR FULL-FACE, SCBA, RUBBERIZED OUTER WEAR, GLOVES, BOOTS. Unusual Fire/Explosion Hazard:SULFURIC ACID WILL NOT BURN BUT CAN START FIRES WITH ORGANIC MATERIAL, NITRATES, CARBIDES, CHLORATES & METAL POWDER. FLAMMABLE HYDROGEN GAS FORMED BY METAL CONTACT. HYDROGEN MAY ACCUMULATE IN CONTAINE RS, AVOID IGNITION SOURCES, SPILL INTO SEWERS MAY GENERATE HYDROGEN OR TOXIC SULFIDES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL ACID-PROTECTIVE GEAR. REMOVE SOURCES OF IGNITION. NEUTRALIZE SPILL WITH LIME OR SODA ASH. FLUSH TO WASTE WATER TREATMENT SYSTEM IF ALLOWED. DIKE LARGE SPILLS. DO NOT WASH INTO STORM OR SANIT ARY SEWER SYSTEM. Neutralizing Agent:LIME OR SODA ASH (MIN 7.8 LBS PER GALLON OF ELECTROLYTE) CONSULT REGULATIONS. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE NEAR ORGANICS. HYDROGEN MAY BE GENERATED INSIDE DRUMS & TANKS. AVOID FLAMES & SPARKS. Other Precautions:NEVER ADD WATER TO CONTAINERS OF ACID. BEWARE OF ACID REACTION IN SEWERS THAT MAY PRODUCE FLAMMABLE HYDROGEN GAS OR TOXIC SULFIDES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN NEEDED USE NIOSH OR MSHA APPROVED HALF OR FULL-FACE MASK WITH ACID GAS CARTRIDGE. FOR HIGH CONCENTRATIONS, USE SELF-CONTAINED BREATHING APPARATUS. Ventilation:REQUIRED. USE LOCAL EXHAUST. NOTE:VENTILATE STORAGE TANKS BEFORE ENTERING. Protective Gloves:RUBBER Eye Protection:CHEMICAL GOGGLES OR FULL FACE SHIELD. Other Protective Equipment:RUBBER SAFETY SHOES/BOOTS. RUBER APRON OR FULL SUIT IF SPLASHES LIKELY. Work Hygienic Practices:PROHIBIT SMOKING. PROVIDE SAFETY SHOWERS/EYE WASHES NEAR WORK SITE. TRAIN EMPLOYEES IN CHEMICAL HANDLING PRACTICES. Supplemental Safety and Health SPEED REMOVING ACID IS ESSENTIAL!! TREAT MOST URGENT SYMPTOMS FIRST. CESSATION OF BREATHING,EYE INJURY,SKIN CONTACT,SHOCK. SEEK MEDICAL ASSISTANCE EVEN IF INJURY APPEARS SLIGHT. DURING TRANSPROT TO ME DICAL FACILITY, APPLY COLD COMPRESSES. IMMERSE AREA IN ICE WATER. AVOID FREEZING TISSUES. CONTINUE WASHING AFFECTED AREA ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NONE Boiling Pt:=135.C, 275.F Melt/Freeze Pt:=-62.2C, -80.F Vapor Pres:< 1 Vapor Density:3.4 (AIR=1 Spec Gravity:1.265 pH:< 1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID. Percent Volatiles by Volume:UNK. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS, ORGANICS, NITRATES, CARBIDES, CHLORATES, ALLYL COMPOUNDS, AND ALDEHYDES Stability Condition to Avoid:CONTACT WITH METALS, ORGANICS. Hazardous Decomposition Products:SULFUR OXIDES AT HIGH TEMPERATURE. REACTS W/ABOVE TO FORM HYDROGEN CYANIDE & HYDROGEN SULFIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. AVOID ALL CONTACT WITH ORGANIC SUBSTANCES AND MOST METALS. ===================== Ecological Information ===================== Ecological:REPORTABLE QUANTITY= 1000 LBS AS H2S04. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZE W/LIME OR SODA ASH. CONSULT REGULATIONS. EPA HAZARDOUS WASTE D002- CORROSIVE & D003-REACTIVE IF DISCARDED W/O PRIOR NEUTRALIZATION. =================== MSDS Transport Information =================== Transport Information:DOT PSN: BATTERY FLUID ACID. CLASS 8, UN2796. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.