ANACHEMIA CHEMICALS INC -- HYDROCHLORIC ACID -- -
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID MSDS Date:07/20/1999 FSC:NIIN:Submitter:D DG === Responsible Party === Company Name:ANACHEMIA CHEMICALS INC Address:3 LINCOLN BLVD City:ROUSES POINT State:NY ZIP:12979 Country:US Info Phone Num:518-297-4444 Emergency Phone Num:(800)424-9300 Preparer's Name:MSDS DEPT Chemtrec Ind/Phone:(800)424-9300 CAGE:4A444 === Contractor Identification === Company Name:ANACHEMIA CANADA Address:255 NORMAN H8R 1A3 Box:City:VILLE ST. PIERRE (MONTREAL) State:PQ Country:CN Phone:514-489-5711;518-297-4444 CAGE:36842 Company Name:ANACHEMIA CHEMICALS INC Address:3 LINCOLN BLVD Box:City:ROUSES POINT State:NY ZIP:12979 Country:US Phone:518-297-4444 CAGE:4A444 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-0959 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-0962 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-4747 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-4772 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-01-P-0018 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-01-P-0065 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-01-P-2037 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-99-P-1403 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-99-P-3287 CAGE:0X801 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID (AS HCL) CAS:7647-01-0 RTECS #:MW4025000 Minumum % Wt:30. Maxumum % Wt:38. OSHA PEL:C7 MG/M3;C5 PPM ACGIH TLV:5 PPM, 7.5 MG/M3 ACGIH STEL:C7.5 MG/M3;C5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (RABBIT) LD50: 900 MG/KG (HCL) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF ACUTE EXPOSURE: HARMFUL BY INGESTION, INHALATION/SKIN ABSORPTION. CORROSIVE. TARGET ORGANS: SKIN, EYES, LUNGS, RESPIRTORY SYSTEM. 100 PPM IS IMMEDIATELY DANGEROUS TO LIFE. EYE: EXTREMELY CO RROSIVE AND SEVERELY IRRITATING. PROLONGED CONTACT MAY CAUSE BLINDNESS. SKIN: CAUSES SEVERE BURNS, SEVERE PAIN, DERMATITIS, PHOTOSENSITIZATION. INHALATION: EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS ME MBRANES. MAY BE FATAL. CAUSES BURNING, COUGHING, LARYNGITIS, HEADACHE, LUNG DAMAGE. INGESTION: BURNS, NAUSEA, VOMITING, ABDOMINAL PAIN, COLLAPSE, COMA, AND DEATH POSSIBLE. CHRONIC: EROSION OF TEETH, B RONCHITIS. SEVERE DERMATITIS/BURNS. Explanation of Carcinogenicity:CARCINOGENIC EFFECTS: NOT AVAILABLE. Effects of Overexposure:EYE: EXTREMELY CORROSIVE AND SEVERELY IRRITATING. PROLONGED CONTACT MAY CAUSE BLINDNESS. SKIN: CAUSES SEVERE BURNS, SEVERE PAIN, DERMATITIS, PHOTOSENSITIZATION. INHALATION: EXTREMELY DESTRUCTIVE TO TI SSUE OF MUCOUS MEMBRANES. MAY BE FATAL. CAUSES BURNING, COUGHING, LARYNGITIS, HEADACHE, LUNG DAMAGE. INGESTION: BURNS, NAUSEA, VOMITING, ABDOMINAL PAIN, COLLAPSE, COMA, AND DEATH POSSIBLE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 30 MINUTES HOLDING LIDS APART. SEEK IMMEDIATE MEDICAL ATTN. DO NOT USE CHEMICAL ANTIDOTES. SKIN CONTACT: IMMEDIATELY FLUSH WIT H PLENTY OF WATER FOR AT LEAST 30 MINUTES WHILE REMOVING CONTAMINATED CLOTHES/SHOES. DO NOT USE CHEMICAL ANTIDOTES. SEEK IMMEDIATE MEDICAL ATTN. INHALATION: REMOVE VICTIM TO FRESH AIR. ADMINISTER APPR OVED OXYGEN SUPPLY IF BREATHING DIFFICULT. ADMINISTER RESPIRATION OR CPR IF BREATHING CEASED. INGESTED: IF CONSCIOUS, WASH MOUTH OUT WITH WATER; DRINK SEVERAL GLASSES OF WATER. DO NOT INDUCE VOMITIN G! SEEK IMMEDIATE MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING MATERIALS. WEAR ADEQUATE PERSONAL PROTECTION TO PREVENT CONTACT WITH MATERIAL OR ITS COMBUSTION PRODUCTS. Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. COOL CONTAINING VESSELS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. DO NOT GET WATER INSIDE CONTAINER. Unusual Fire/Explosion Hazard:FLAMMABLE/EXPLOSIVE HYDROGEN GAS MAY BE FORMED UPON CONTACT OF THIS PRODUCT WITH METALS. THE SENSITIVITY TO IMPACT IS NOT APPLICABLE. THE SENSITIVITY TO STATIC DISCHARGE IS NOT APPLICABLE. EMITS TOXI C AND CORROSIVE FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AND VENTILATE THE AREA. COVER WITH SODA ASH OR LIME. THIS WILL RELEASE CARBON DIOXIDE, SO USE CAUTION. PLACE IN A SUITABLE CONTAINER AND MARK FOR DISPOSAL. WASH SPILL SITE AFTER MATERIAL PICK UP IS COMPLETE. DO NOT EMPTY INTO DRAINS. DO NOT TOUCH DAMAGED CONTAINER OR SPILLED MATERIAL. STAY UPWIND: KEEP OUT OF LOW AREAS. Neutralizing Agent:SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM INCOMPATIBLES, HEAT, SPARKS & FLAME. STORE IN A WELL VENTILATED AREA. DO NOT ADD ANY OTHER MATERIAL TO CONTAINER. DO NOT WASH DOWN THE DRAIN. DO NOT BREATHE GAS/FUMES/V APOR/SPARY. IN CASE OF INSUFFICIENT VENTILATION, USE SUITABLE RESPIRATORY EQUIPMENT. Other Precautions:KEEP AWAY FROM DIRECT SUNLIGHT. KEEP CONTAINER TIGHTLY CLOSED & DRY. MANIPULATE UNDER AN ADEQUATE FUME HOOD. PROTECT FROM MOISTURE. DO NOT USE PRESSURE TO DISPENSE. MAY CORRODE METALLIC SURFACES. EMPT Y CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE. HANDLE & OPEN CONTAINER WITH CARE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF HANDLED IN CLOSED VENTILATION SYSTEM. WHERE REQUIRED, USE A NIOSH-APPROVED CHEMICAL CARTRIDGE RESPIRATOR FOR GAS BELOW 50 PPM. FOR GAS ABOVE 50 PPM, USE SELF-CONTAINED BREATHING APPAR ATUS OR AIR-SUPPLIED RESPIRATOR, BOTH WITH FULL FACE PIECE. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. DO NOT USE IN UNVENTILATED SPACE. Protective Gloves:IMPERVIOUS GLOVES (NEOPRENE). Eye Protection:FACE SHIELD AND SPLASH GOGGLES. Other Protective Equipment:NEOPRENE APRON, COVERALLS, AND/OR OTHER RESISTANT PROTECTIVE CLOTHING AS REQUIRED FOR WORKPLACE CONDITIONS TO PREVENT CONTACT WITH HYDROCHLORIC ACID SOLUTIONS. Work Hygienic Practices:WASH WELL AFTER USE. DO NOT ALLOW SMOKING & FOOD CONSUMPTION WHILE HANDLING. WEAR SUITABLE PROTECTIVE CLOTHING. Supplemental Safety and Health P/N: A85; 500ML. OTHER PROTECTION CONT: MAKE EYE WASH & EMERGENCY SHOWER AVAILABLE FOR EMERGENCY USE. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:>108.C, 226.4F B.P. Text:108-110C Melt/Freeze Pt:=-46.2C, -51.F M.P/F.P Text:-46.2 TO -25.4 Decomp Temp:Decomp Text:NOT PROVIDED. Vapor Pres:150-160 MM OF HG@20C Vapor Density:1.3 Spec Gravity:1.19 TO 1.16 pH:0.1 (1%) Evaporation Rate & Reference:>1 Solubility in Water:MISCIBLE IN WATER Appearance and Odor:COLORLESS FUMING LIQUID WITH A PUNGENT ODOR. Percent Volatiles by Volume:100 Corrosion Rate:NOT PROVIDED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MOST COMMON METALS, AMINES, METAL OXIDES, ACETIC ANHYDRIDE, BETA-PROPIOLACETONE, VINYL ACETATE, MERCURIC SULFATE, CALCIUM PHOSPHIDE, FORMALDEHYDE, ALKALIES, CARBONATES, BASES, SULFURIC ACID, CHLOROSULFONIC ACID, NITRIC ACID Stability Condition to Avoid:NONE SPECIFIED BY RESPONSIBLE PARTY. Hazardous Decomposition Products:NOT AVAILABLE. Conditions to Avoid Polymerization:WILL CORRODE A WIDE VARIETY OF METALS. HAZARDOUS POLYMERIZATION WILL NOT OCCUR =================== Toxicological Information =================== Toxicological Information:VAPOR (LC50): ACUTE: 3124 PPM (RAT) (1 HOUR). 757 PPM (MOUSE) (1 HOUR). VAPOR (LCL0): ACUTE: 1300 PPM (HUMAN) (30M). HARMFUL BY INGESTION, INHALATION OR SKIN ABSORPTION. CORROSIVE. TARGET ORGANS: SKIN , EYES, LUNGS, RESPIRTORY SYSTEM. 100 PPM IS IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. EYE-VAPORS, LIQUIDS & MISTS ARE EXTREMELY CORROSIVE TO THE EYES.BRIEF CONTACT OF THE VAPORS WILL BE SEVERELY IRRIT ATING. BRIEF CONTACT OF THE LIQUID OR MIST WILL SEVERELY DAMAGE THE EYES AND PROLONGED CONTACT MAY CAUSE PERMANENT EYE INJURY WHICH MAY BE FOLLOWED BY BLINDNESS. ===================== Ecological Information ===================== Ecological:NONE SPECIFIED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO ALL APPLICABLE REGULATIONS. HARMFUL TO AQUATIC LIFE AT HIGH CONCENTRATIONS. CAN BE DANGEROUS IF ALLOWED TO ENTER DRINKING WATER INTAKES. DO NOT CONTAMINATE DOMESTIC OR IRRIGATION WATER SU PPLIES, LAKES, STREAMS, PONDS, OR RIVERS. =================== MSDS Transport Information =================== Transport Information:CLASS 8, UN 1789, PG II. ===================== Regulatory Information ===================== SARA Title III Information:NONE SPECIFIED BY RESPONSIBLE PARTY. Federal Regulatory Information:NONE SPECIFIED BY RESPONSIBLE PARTY. State Regulatory Information:NONE SPECIFIED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.