GENERAL CHEM CORP (PROD PREV OWNED BY ALLIED CHEM) -- HYDROCHLORIC ACID -- 6810-00N011553
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID MSDS Date:09/01/1986 FSC:6810 NIIN:00N011553 === Responsible Party === Company Name:GENERAL CHEM CORP (PROD PREV OWNED BY ALLIED CHEM) Address:90 E HALSEY Box:395 City:PARSIPPANY State:NY ZIP:07054 Country:US Info Phone Num:800-631-8050 Emergency Phone Num:800-631-8050 CAGE:HO700 === Contractor Identification === Company Name:GENERAL CHEM CORP (PROD PREV OWNED BY ALLIED CHEM) Address:90 E HALSEY Box:395 City:PARSIPPANY State:NY ZIP:07054 Country:US Phone:800-631-8050 CAGE:HO700 Company Name:GENERAL CHEMICAL CORPORATION Address:90 EAST HALSEY ROAD Box:City:PARSIPPANY State:NJ ZIP:07054 Country:US Phone:973-515-1840 CAGE:0AU44 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III) CAS:7647-01-0 RTECS #:MW4025000 Other REC Limits:N/K OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 RABBIT ORAL 900 MG/KG. (SEE SUPP) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CAN COMPLETELY DESTROY MUCOUS MEMBRANES DURING INHALATION.INGESTION:SEVERE BURNING OF MOUTH,PHARYNX,ABDOMEN.ASPHYXIA MAY OCCUR FROM EDEMA OF GLOTTIS.DERMATITIS & PHOTOSENSITIZATION.CONJUNCTIVAL EDEMA & CORNEAL DESTRUCTION MAY CAUSE BLINDNESS.POISON-INGESTION MAY BE FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:CONJUNC EDEMA & CORNEAL DESTRUCTION POSS CAUSING BLINDNESS.PAIN,TEARING,PHOTOPHOBIA.VAP IS IRRIT.SKIN:SEV PAIN,BROWNISH/YELLOW STAINS.PENETRATES SKIN.DERM,PHOTOSENSITIZATION.INGEST:SEV BURNS OF M OUTH,PHARYNX,ABDOMEN,VOMIT,WEAKNESS,ASPHYXIA.POSS FATAL.INHAL:DESTRUCT OF MUC MEMB,CHOKING,COUGH,HDCH,DIZZ.PULM EDEMA. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/ H*2O 20-30 MIN,HOLDING LIDS OPEN.CALL MD.USE NO CHEM ANTIDOTE.SKIN:IMMED FLUSH W/ H*2O FOR AT LEAST 15 MIN.REMOVE CONTAM CLTHG.USE NO CHEM ANTIDOTES.CALL MD.PH >3 PROMPT WASHING NE C.INGEST:IMMED DRINK LRG AMT H*2O/MILK TO DILUTE 100X;REPEAT IF VOMIT.DO NOT INDUCE VOMIT.CALL MD.INH:IMMED MOVE TO FRESH AIR.DFCLT BRTHG-GIVE O*2.BRTHG STOPS-GIVE ARTF RESP.SYMP PERSIST-GET MED HELP. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF INVOLVED IN A FIRE,USE WATER.ALSO MAY NEUTRALIZE WITH ALKALIS SUCH AS SODA ASH OR LIME. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.DO NOT SPLASH THIS MATL ONTO OTHER PERSONNEL. Unusual Fire/Explosion Hazard:CO*2 POSS DURING NEUT.CONT W/ METALS MAY GENERATE HYDROGEN GAS-A SERIOUS FIRE/EXPLO HAZARD.HCL EVOLUTION INCR BY HEAT/CONT W/ WATER-REACTIVE MATLS.TOXIC GASES. ================== Accidental Release Measures ================== Spill Release Procedures:EYE-PROTECTED PERSONNEL SHOULD REMOVE SPILLS IMMEDIATELY BY FLUSHING AWAY WITH LOTS OF WATER.FULLY PROTECTED (INCLUDING FACESHLD) PERS MAY CAREFULLY NEUTRALIZE W/ ALKALIS SUCH AS SODA ASH OR LIME.USE AMPLE VENT WHEN NEUTRALIZING TO ELIM CO*2 FORMED. Neutralizing Agent:ALKALIS SUCH AS SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONT W/ SKIN/EYES/CLTHG/INHAL OF VAP.KEEP AWAY FROM METALS,INCOMPATIBLE CHEMS.STORE IN DRY,WELL-VENT AREA,AWAY FROM HEAT,FLAM MATLS,OUT OF SUN. Other Precautions:PROT FROM PHYS DMG & KEEP CONTR CLSD & UPRIGHT.CORR MATL.DANGER CAUSES BURNS.POSS FATAL IF INGEST.POISON.REC MED SURVEILLANCE & PERS EDUCATION.NO FLAMES,SPARKS,SMOKING IN STORE AREA.VENT PACKAGING,UNL OADING,OPEN PROCESSING AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Protective Gloves:ACID-RESISTANT GAUNTLET GLOVES. Eye Protection:CHEM WORK GOGG,WITH FACESHIELD . Other Protective Equipment:ACID-RESIST (NEOPRENE OR NITRILE-BUTADIENE RUB) APRON,TROUSERS & JACKET,BOOTS.EYEWASH & QUICK-DRENCH. Work Hygienic Practices:NO CONT LENSES.IMMED WASH CONTAM IMPERVIOUS ITEMS.IMMED REMOVE CONTAM NON-IMPERVIOUS ITEMS. Supplemental Safety and Health VP:30 MMHG @ 25C,77F.VAP DENS:EST 1.3 (AIR=1).PH:1N-0.1,0.1N-1.1,0.02N-2.02,0.002N-3.02.MATLS TO AVOID:H*2O-REACTIVE MATLS (CONC H*2SO*4),OLEUM,ACETIC ANHYDRIDE.CARBONATES,CYANIDES,SULFIDES LIBERATE T OX GASES.RTS OF ENTRY:ALL .LD50-LC50 MIX:LC50 RAT INHAL 3124 PPM/1 HR. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:51C,122F Melt/Freeze Pt:M.P/F.P Text:-74C,-101F Decomp Temp:Decomp Text:N/K Vapor Pres:SEE SUPP Vapor Density:SEE SUPP Spec Gravity:1.19 (WATER=1) pH:SUP DA Evaporation Rate & Reference:>1 (ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID WITH PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS,ALKALIS,METALLIC OXIDES,AMINES,STRONG OXIDANTS (FL),VINYL ACETATE,PROPIOLACETONE (BETA),PROPYLENE OXIDE (SUP DA) Stability Condition to Avoid:N/K Hazardous Decomposition Products:HCL EVOLUTION ACCELERATED BY HEAT OR CONT W/ WATER-REACTIVE MATLS (CONCENTRATED H*2SO*4).CO*2 DURING NEUT.TOX GASES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.